王心超,彭一燕.热塑性聚氨酯纳米粘土复合泡沫结构与性能的研究[J].精密成形工程,2016,8(1):43-49,78. Xin-chao WANG,Yi-yan PENG.Study of Microstructure and Properties of Thermal Polyurethane Nanocomposite Foams[J].Journal of Netshape Forming Engineering,2016,8(1):43-49,78. |
热塑性聚氨酯纳米粘土复合泡沫结构与性能的研究 |
Study of Microstructure and Properties of Thermal Polyurethane Nanocomposite Foams |
投稿时间:2015-09-16 修订日期:2016-01-10 |
DOI:10.3969/j.issn.1674-6457.2016.01.008 |
中文关键词: 微发泡 热塑性聚氨酯 微发泡注塑成型 纳米粘土复合泡沫 |
英文关键词: microcellular structure thermal polyurethane foam nanoclay MuCell injection moldi |
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中文摘要: |
要研究了纳米粘土含量对热塑性聚氨酯 (TPU) 复合泡沫的结构与性能的影响。通过扫描电镜 (SEM) 观察TPU泡沫的微孔结构发现: 随着纳米粘土含量的增加, 微孔的直径显著减小且数量明显增加。拉伸测试发现纳米粘土含量增加到5%(质量分数)时, TPU复合泡沫的力学性能增加了56.3%, 而复合泡沫的密度却减小了12.5%。研究认为可以通过改变纳米填料的含量, 来调节聚合物复合泡沫的微观结构和机械性能, 这对微孔聚合物泡沫的工业生产有着重要的指导意义。 |
英文摘要: |
The microstructure and mechanical properties of thermoplastic polyurethane(TPU)with organic modified clay nano?composite foams were studied by scanning electron microscopy(SEM)and mechanical tests. The cell diameters of the TPU/clay foams became smaller,and the cell numbers significantly increased as the clay content increased. The relationship between clay content and the mechanical properties of TPU/clay foams was also investigated. The results showed that the mass density of nanocomposite foams was lowered by 12.5 wt% when the clay loading level was 5 wt% in the nanocomposite foams. Meanwhile, the tensile strength at 300% strain of the nanocomposite foams with 5 wt% clay increased by 56.3% compared to pure TPU. This study shows that light weight,high strength TPU/clay nanocomposite foams can be produced by loading a moderate amount of clay into the TPU matrix. |
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